Raman spectroscopy associated with chemometrics for determining Origanum oil adulteration
Аутори
Kolašinac, StefanŠoštarić, Ivan
Ćujić, Svetlana
Bošnjak-Neumüller, Jasna
Dajić Stevanović, Zora
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Essential oils (EOs) are complex mixtures of volatile and semivolatile compounds (aldehydes, ketones, alcohols and esters) obtained usually by hydro-distillation from the dry or fresh plant material (seeds, leaves, stems, bark or wood) [1]. Most of the EOs are used in aroma therapy, plant protection (as pesticide), food industry (as food preservatives), perfume industry etc. Because of high demand, EOs are often counterfeited and the quality of EOs is usually controlled by gas chromatography.
The aim of this paper is to analyze Origanum oil and its counterfeits by Raman spectroscopy. As an adulterant sunflower oil was used. Adulterated essential oils contained 1, 2, 5, 10, 20, 30, 40, 50, 60, 70, 80, 90 % of sunflower oil. Raman spectra of pure Origano oil and its counterfeits were measured by Witec R300 system equipped with 532 nm laser. Visual inspection of raw spectra led to conclusion that band at 2851 cm-1 is a marker for sunflower oil presence in Origanum oil. However, this ban...d was obvious only when concentration of sunflower oil is higher than, or equal to 10% and could not be seen in lower concentration. In order to reveal presence of this this band in lower concentration, region between 2800 and 3000 cm-1 was subjected to derivatization and then smoothing. Results displayed that Raman spectroscopy in combination with mathematical transformation of spectra can reveal small concentration of unwanted adulterant in Origanum oil.
Извор:
5th INTERNATIONAL CONFERENCE ON NATURAL PRODUCTS UTILIZATION, 2023, 189-189Финансирање / пројекти:
- info:eu-repo/grantAgreement/MESTD/inst-2020/200116/RS//"> <locale name="en (RS-MESTD-inst-2020-200116)
Институција/група
Poljoprivredni fakultetTY - CONF AU - Kolašinac, Stefan AU - Šoštarić, Ivan AU - Ćujić, Svetlana AU - Bošnjak-Neumüller, Jasna AU - Dajić Stevanović, Zora PY - 2023 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/6510 AB - Essential oils (EOs) are complex mixtures of volatile and semivolatile compounds (aldehydes, ketones, alcohols and esters) obtained usually by hydro-distillation from the dry or fresh plant material (seeds, leaves, stems, bark or wood) [1]. Most of the EOs are used in aroma therapy, plant protection (as pesticide), food industry (as food preservatives), perfume industry etc. Because of high demand, EOs are often counterfeited and the quality of EOs is usually controlled by gas chromatography. The aim of this paper is to analyze Origanum oil and its counterfeits by Raman spectroscopy. As an adulterant sunflower oil was used. Adulterated essential oils contained 1, 2, 5, 10, 20, 30, 40, 50, 60, 70, 80, 90 % of sunflower oil. Raman spectra of pure Origano oil and its counterfeits were measured by Witec R300 system equipped with 532 nm laser. Visual inspection of raw spectra led to conclusion that band at 2851 cm-1 is a marker for sunflower oil presence in Origanum oil. However, this band was obvious only when concentration of sunflower oil is higher than, or equal to 10% and could not be seen in lower concentration. In order to reveal presence of this this band in lower concentration, region between 2800 and 3000 cm-1 was subjected to derivatization and then smoothing. Results displayed that Raman spectroscopy in combination with mathematical transformation of spectra can reveal small concentration of unwanted adulterant in Origanum oil. C3 - 5th INTERNATIONAL CONFERENCE ON NATURAL PRODUCTS UTILIZATION T1 - Raman spectroscopy associated with chemometrics for determining Origanum oil adulteration EP - 189 SP - 189 UR - https://hdl.handle.net/21.15107/rcub_agrospace_6510 ER -
@conference{ author = "Kolašinac, Stefan and Šoštarić, Ivan and Ćujić, Svetlana and Bošnjak-Neumüller, Jasna and Dajić Stevanović, Zora", year = "2023", abstract = "Essential oils (EOs) are complex mixtures of volatile and semivolatile compounds (aldehydes, ketones, alcohols and esters) obtained usually by hydro-distillation from the dry or fresh plant material (seeds, leaves, stems, bark or wood) [1]. Most of the EOs are used in aroma therapy, plant protection (as pesticide), food industry (as food preservatives), perfume industry etc. Because of high demand, EOs are often counterfeited and the quality of EOs is usually controlled by gas chromatography. The aim of this paper is to analyze Origanum oil and its counterfeits by Raman spectroscopy. As an adulterant sunflower oil was used. Adulterated essential oils contained 1, 2, 5, 10, 20, 30, 40, 50, 60, 70, 80, 90 % of sunflower oil. Raman spectra of pure Origano oil and its counterfeits were measured by Witec R300 system equipped with 532 nm laser. Visual inspection of raw spectra led to conclusion that band at 2851 cm-1 is a marker for sunflower oil presence in Origanum oil. However, this band was obvious only when concentration of sunflower oil is higher than, or equal to 10% and could not be seen in lower concentration. In order to reveal presence of this this band in lower concentration, region between 2800 and 3000 cm-1 was subjected to derivatization and then smoothing. Results displayed that Raman spectroscopy in combination with mathematical transformation of spectra can reveal small concentration of unwanted adulterant in Origanum oil.", journal = "5th INTERNATIONAL CONFERENCE ON NATURAL PRODUCTS UTILIZATION", title = "Raman spectroscopy associated with chemometrics for determining Origanum oil adulteration", pages = "189-189", url = "https://hdl.handle.net/21.15107/rcub_agrospace_6510" }
Kolašinac, S., Šoštarić, I., Ćujić, S., Bošnjak-Neumüller, J.,& Dajić Stevanović, Z.. (2023). Raman spectroscopy associated with chemometrics for determining Origanum oil adulteration. in 5th INTERNATIONAL CONFERENCE ON NATURAL PRODUCTS UTILIZATION, 189-189. https://hdl.handle.net/21.15107/rcub_agrospace_6510
Kolašinac S, Šoštarić I, Ćujić S, Bošnjak-Neumüller J, Dajić Stevanović Z. Raman spectroscopy associated with chemometrics for determining Origanum oil adulteration. in 5th INTERNATIONAL CONFERENCE ON NATURAL PRODUCTS UTILIZATION. 2023;:189-189. https://hdl.handle.net/21.15107/rcub_agrospace_6510 .
Kolašinac, Stefan, Šoštarić, Ivan, Ćujić, Svetlana, Bošnjak-Neumüller, Jasna, Dajić Stevanović, Zora, "Raman spectroscopy associated with chemometrics for determining Origanum oil adulteration" in 5th INTERNATIONAL CONFERENCE ON NATURAL PRODUCTS UTILIZATION (2023):189-189, https://hdl.handle.net/21.15107/rcub_agrospace_6510 .