Brushite-Metakaolin Composite Geopolymer Material as an Effective Adsorbent for Lead Removal from Aqueous Solutions
Аутори
Djukić, DunjaKrstić, Aleksandar
Jakovljević, Ksenija
Butulija, Svetlana
Andjelković, Ljubica
Pavlović, Vladimir
Mirković, Miljana
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Newly designed mesoporous brushite-metakaolin-based geopolymer materials were examined with an idea for using this material as a potential adsorbent for Pb(II) removal from aqueous solutions. As a starting component for geopolymer synthesis, a natural raw kaolinite clay with the addition of 2 wt.%, 4 wt.%, 6 wt.%, 8 wt.%, and 10 wt.% of pure brushite was used. Phase, structural, morphological, and adsorption properties of newly synthesized mesoporous brushite-metakaolin geopolymer materials were examined in detail by the means of XRPD, FTIR, SEM-EDS, BET/BJH, and ICP-OES methods. The ICP-OES results showed that the synthesized material samples with 2 wt.%, 4 wt.%, and 6 wt.% of brushite possess significant adsorption properties and the mechanisms of the adsorption process can be attributed to chemisorption. The most notable result is that brushite-metakaolin-geopolymer with 2 wt.% of brushite have the best efficiency removal, more than 85% of Pb(II).
Кључне речи:
alkali-activated materials / environmentally friendly / high lead removal efficiency / natural adsorbentsИзвор:
Sustainability (Switzerland), 2022, 14, 7, 4003-Издавач:
- MDPI
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200017 (Универзитет у Београду, Институт за нуклеарне науке Винча, Београд-Винча) (RS-MESTD-inst-2020-200017)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200026 (Универзитет у Београду, Институт за хемију, технологију и металургију - ИХТМ) (RS-MESTD-inst-2020-200026)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200116 (Универзитет у Београду, Пољопривредни факултет) (RS-MESTD-inst-2020-200116)
DOI: 10.3390/su14074003
ISSN: 2071-1050
WoS: 000781394300001
Scopus: 2-s2.0-85127847783
Институција/група
Poljoprivredni fakultetTY - JOUR AU - Djukić, Dunja AU - Krstić, Aleksandar AU - Jakovljević, Ksenija AU - Butulija, Svetlana AU - Andjelković, Ljubica AU - Pavlović, Vladimir AU - Mirković, Miljana PY - 2022 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/6067 AB - Newly designed mesoporous brushite-metakaolin-based geopolymer materials were examined with an idea for using this material as a potential adsorbent for Pb(II) removal from aqueous solutions. As a starting component for geopolymer synthesis, a natural raw kaolinite clay with the addition of 2 wt.%, 4 wt.%, 6 wt.%, 8 wt.%, and 10 wt.% of pure brushite was used. Phase, structural, morphological, and adsorption properties of newly synthesized mesoporous brushite-metakaolin geopolymer materials were examined in detail by the means of XRPD, FTIR, SEM-EDS, BET/BJH, and ICP-OES methods. The ICP-OES results showed that the synthesized material samples with 2 wt.%, 4 wt.%, and 6 wt.% of brushite possess significant adsorption properties and the mechanisms of the adsorption process can be attributed to chemisorption. The most notable result is that brushite-metakaolin-geopolymer with 2 wt.% of brushite have the best efficiency removal, more than 85% of Pb(II). PB - MDPI T2 - Sustainability (Switzerland) T1 - Brushite-Metakaolin Composite Geopolymer Material as an Effective Adsorbent for Lead Removal from Aqueous Solutions IS - 7 SP - 4003 VL - 14 DO - 10.3390/su14074003 ER -
@article{ author = "Djukić, Dunja and Krstić, Aleksandar and Jakovljević, Ksenija and Butulija, Svetlana and Andjelković, Ljubica and Pavlović, Vladimir and Mirković, Miljana", year = "2022", abstract = "Newly designed mesoporous brushite-metakaolin-based geopolymer materials were examined with an idea for using this material as a potential adsorbent for Pb(II) removal from aqueous solutions. As a starting component for geopolymer synthesis, a natural raw kaolinite clay with the addition of 2 wt.%, 4 wt.%, 6 wt.%, 8 wt.%, and 10 wt.% of pure brushite was used. Phase, structural, morphological, and adsorption properties of newly synthesized mesoporous brushite-metakaolin geopolymer materials were examined in detail by the means of XRPD, FTIR, SEM-EDS, BET/BJH, and ICP-OES methods. The ICP-OES results showed that the synthesized material samples with 2 wt.%, 4 wt.%, and 6 wt.% of brushite possess significant adsorption properties and the mechanisms of the adsorption process can be attributed to chemisorption. The most notable result is that brushite-metakaolin-geopolymer with 2 wt.% of brushite have the best efficiency removal, more than 85% of Pb(II).", publisher = "MDPI", journal = "Sustainability (Switzerland)", title = "Brushite-Metakaolin Composite Geopolymer Material as an Effective Adsorbent for Lead Removal from Aqueous Solutions", number = "7", pages = "4003", volume = "14", doi = "10.3390/su14074003" }
Djukić, D., Krstić, A., Jakovljević, K., Butulija, S., Andjelković, L., Pavlović, V.,& Mirković, M.. (2022). Brushite-Metakaolin Composite Geopolymer Material as an Effective Adsorbent for Lead Removal from Aqueous Solutions. in Sustainability (Switzerland) MDPI., 14(7), 4003. https://doi.org/10.3390/su14074003
Djukić D, Krstić A, Jakovljević K, Butulija S, Andjelković L, Pavlović V, Mirković M. Brushite-Metakaolin Composite Geopolymer Material as an Effective Adsorbent for Lead Removal from Aqueous Solutions. in Sustainability (Switzerland). 2022;14(7):4003. doi:10.3390/su14074003 .
Djukić, Dunja, Krstić, Aleksandar, Jakovljević, Ksenija, Butulija, Svetlana, Andjelković, Ljubica, Pavlović, Vladimir, Mirković, Miljana, "Brushite-Metakaolin Composite Geopolymer Material as an Effective Adsorbent for Lead Removal from Aqueous Solutions" in Sustainability (Switzerland), 14, no. 7 (2022):4003, https://doi.org/10.3390/su14074003 . .