Production of bacterial nanocellulose (BNC) and its application as a solid support in transition metal catalysed cross-coupling reactions
2019
Autori
Jeremić, SanjaDjokić, Lidija
Ajdacić, Vladimir
Božinović, Nina
Pavlović, Vladimir
Manojlović, Dragan
Babu, Ramesh
Senthamaraikannan, Ramsankar
Rojas, Orlando
Opsenica, Igor
Nikodinović-Runić, Jasmina
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Bacterial nanocellulose (BNC) emerged as an attractive advanced biomaterial that provides desirable properties such as high strength, lightweight, tailorable surface chemistry, hydrophilicity, and biodegradability. BNC was successfully obtained from a wide range of carbon sources including sugars derived from grass biomass using Komagataeibacter medellinensis ID13488 strain with yields up to 6 g L-1 in static fermentation. Produced BNC was utilized in straightforward catalyst preparation as a solid support for two different transition metals, palladium and copper with metal loading of 20 and 3 wt%, respectively. Sustainable catalysts were applied in the synthesis of valuable fine chemicals, such as biphenyl-4-amine and 4'-fluorobiphenyl-4-amine, used in drug discovery, perfumes and dye industries with excellent product yields of up to 99%. Pd/BNC catalyst was reused 4 times and applied in two consecutive reactions, Suzuki-Miyaura cross-coupling reaction followed by hydrogenation of nit...ro to amino group while Cu/BNC catalyst was examined in Chan-Lam coupling reaction. Overall, the environmentally benign process of obtaining nanocellulose from biomass, followed by its utilisation as a solid support in metal-catalysed reactions and its recovery has been described. These findings reveal that BNC is a good support material, and it can be used as a support for different catalytic systems.
Ključne reči:
Bacterial nanocellulose / Komagataeibacter medellinensis / Cross-coupling reactions, catalysisIzvor:
International Journal of Biological Macromolecules, 2019, 129, 351-360Izdavač:
- Elsevier, Amsterdam
Finansiranje / projekti:
- Sinteza aminohinolina i njihovih derivata kao antimalarika i inhibitora botulinum neurotoksina A (RS-172008)
- Izučavanje mikrobiološkog diverziteta i karakterizacija korisnih sredinskih mikroorganizama (RS-173048)
DOI: 10.1016/j.ijbiomac.2019.01.154
ISSN: 0141-8130
PubMed: 30710586
WoS: 000466621200037
Scopus: 2-s2.0-85061444472
Institucija/grupa
Poljoprivredni fakultetTY - JOUR AU - Jeremić, Sanja AU - Djokić, Lidija AU - Ajdacić, Vladimir AU - Božinović, Nina AU - Pavlović, Vladimir AU - Manojlović, Dragan AU - Babu, Ramesh AU - Senthamaraikannan, Ramsankar AU - Rojas, Orlando AU - Opsenica, Igor AU - Nikodinović-Runić, Jasmina PY - 2019 UR - http://aspace.agrif.bg.ac.rs/handle/123456789/5066 AB - Bacterial nanocellulose (BNC) emerged as an attractive advanced biomaterial that provides desirable properties such as high strength, lightweight, tailorable surface chemistry, hydrophilicity, and biodegradability. BNC was successfully obtained from a wide range of carbon sources including sugars derived from grass biomass using Komagataeibacter medellinensis ID13488 strain with yields up to 6 g L-1 in static fermentation. Produced BNC was utilized in straightforward catalyst preparation as a solid support for two different transition metals, palladium and copper with metal loading of 20 and 3 wt%, respectively. Sustainable catalysts were applied in the synthesis of valuable fine chemicals, such as biphenyl-4-amine and 4'-fluorobiphenyl-4-amine, used in drug discovery, perfumes and dye industries with excellent product yields of up to 99%. Pd/BNC catalyst was reused 4 times and applied in two consecutive reactions, Suzuki-Miyaura cross-coupling reaction followed by hydrogenation of nitro to amino group while Cu/BNC catalyst was examined in Chan-Lam coupling reaction. Overall, the environmentally benign process of obtaining nanocellulose from biomass, followed by its utilisation as a solid support in metal-catalysed reactions and its recovery has been described. These findings reveal that BNC is a good support material, and it can be used as a support for different catalytic systems. PB - Elsevier, Amsterdam T2 - International Journal of Biological Macromolecules T1 - Production of bacterial nanocellulose (BNC) and its application as a solid support in transition metal catalysed cross-coupling reactions EP - 360 SP - 351 VL - 129 DO - 10.1016/j.ijbiomac.2019.01.154 ER -
@article{ author = "Jeremić, Sanja and Djokić, Lidija and Ajdacić, Vladimir and Božinović, Nina and Pavlović, Vladimir and Manojlović, Dragan and Babu, Ramesh and Senthamaraikannan, Ramsankar and Rojas, Orlando and Opsenica, Igor and Nikodinović-Runić, Jasmina", year = "2019", abstract = "Bacterial nanocellulose (BNC) emerged as an attractive advanced biomaterial that provides desirable properties such as high strength, lightweight, tailorable surface chemistry, hydrophilicity, and biodegradability. BNC was successfully obtained from a wide range of carbon sources including sugars derived from grass biomass using Komagataeibacter medellinensis ID13488 strain with yields up to 6 g L-1 in static fermentation. Produced BNC was utilized in straightforward catalyst preparation as a solid support for two different transition metals, palladium and copper with metal loading of 20 and 3 wt%, respectively. Sustainable catalysts were applied in the synthesis of valuable fine chemicals, such as biphenyl-4-amine and 4'-fluorobiphenyl-4-amine, used in drug discovery, perfumes and dye industries with excellent product yields of up to 99%. Pd/BNC catalyst was reused 4 times and applied in two consecutive reactions, Suzuki-Miyaura cross-coupling reaction followed by hydrogenation of nitro to amino group while Cu/BNC catalyst was examined in Chan-Lam coupling reaction. Overall, the environmentally benign process of obtaining nanocellulose from biomass, followed by its utilisation as a solid support in metal-catalysed reactions and its recovery has been described. These findings reveal that BNC is a good support material, and it can be used as a support for different catalytic systems.", publisher = "Elsevier, Amsterdam", journal = "International Journal of Biological Macromolecules", title = "Production of bacterial nanocellulose (BNC) and its application as a solid support in transition metal catalysed cross-coupling reactions", pages = "360-351", volume = "129", doi = "10.1016/j.ijbiomac.2019.01.154" }
Jeremić, S., Djokić, L., Ajdacić, V., Božinović, N., Pavlović, V., Manojlović, D., Babu, R., Senthamaraikannan, R., Rojas, O., Opsenica, I.,& Nikodinović-Runić, J.. (2019). Production of bacterial nanocellulose (BNC) and its application as a solid support in transition metal catalysed cross-coupling reactions. in International Journal of Biological Macromolecules Elsevier, Amsterdam., 129, 351-360. https://doi.org/10.1016/j.ijbiomac.2019.01.154
Jeremić S, Djokić L, Ajdacić V, Božinović N, Pavlović V, Manojlović D, Babu R, Senthamaraikannan R, Rojas O, Opsenica I, Nikodinović-Runić J. Production of bacterial nanocellulose (BNC) and its application as a solid support in transition metal catalysed cross-coupling reactions. in International Journal of Biological Macromolecules. 2019;129:351-360. doi:10.1016/j.ijbiomac.2019.01.154 .
Jeremić, Sanja, Djokić, Lidija, Ajdacić, Vladimir, Božinović, Nina, Pavlović, Vladimir, Manojlović, Dragan, Babu, Ramesh, Senthamaraikannan, Ramsankar, Rojas, Orlando, Opsenica, Igor, Nikodinović-Runić, Jasmina, "Production of bacterial nanocellulose (BNC) and its application as a solid support in transition metal catalysed cross-coupling reactions" in International Journal of Biological Macromolecules, 129 (2019):351-360, https://doi.org/10.1016/j.ijbiomac.2019.01.154 . .